Nitrogen Cycle

nitrogen cycle, circulation of nitrogen in various forms through nature. Nitrogen, a component of proteins and nucleic acids, is essential to life on Earth. Although 78 percent by volume of the atmosphere is nitrogen gas, this abundant reservoir exists in a form unusable by most organisms. Through a series of microbial transformations, however, nitrogen is made available to plants, which in turn ultimately sustain all animal life. The steps, which are not altogether sequential, fall into the following classifications: nitrogen fixation, nitrogen assimilation, ammonification, nitrification, and denitrification.

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Nitrogen fixation, in which nitrogen gas is converted into inorganic nitrogen compounds, is mostly (90 percent) accomplished by certain bacteria and blue-green algae. A much smaller amount of free nitrogen is fixed by abiotic means (e.g., lightning, ultraviolet radiation, electrical equipment) and by conversion to ammonia through the Haber-Bosch process.

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Nitrates and ammonia resulting from nitrogen fixation are assimilated into the specific tissue compounds of algae and higher plants. Animals then ingest these algae and plants, converting them into their own body compounds.

The remains of all living things—and their waste products—are decomposed by microorganisms in the process of ammonification, which yields ammonia (NH₃) and ammonium (NH₄+). (Under anaerobic, or oxygen-free, conditions, foul-smelling putrefactive products may appear, but they too are converted to ammonia in time.) Ammonia can leave the soil or be converted into other nitrogen compounds, depending in part on soil conditions.

Nitrification, a process carried out by nitrifying bacteria, transforms soil ammonia into nitrates (NO₃−), which plants can incorporate into their own tissues.

Nitrates also are metabolized by denitrifying bacteria, which are especially active in water-logged anaerobic soils. The action of these bacteria tends to deplete soil nitrates, forming free atmospheric nitrogen.